Bis(5-bromopyridine-2-carboxylato-κO)triphenylantimony(V)
نویسندگان
چکیده
منابع مشابه
catena-Poly[sodium [[tris(3-methylpyridine-2-carboxylato)europate(III)]-μ-3-methylpyridine-2-carboxylato] trihydrate]
In the title structure, {Na[Eu(C(7)H(6)NO(2))(4)]·3H(2)O}(n), the Eu(III) atom is nine-coordin-ated within a slightly distorted tricapped trigonal-prismatic coordination geometry defined by five carboxyl-ate-O atoms and four pyridine-N atoms. One of the carboxyl-ate ligands bridges the Eu cations, forming a one-dimensional coordination polymer along the b axis. The Eu-O bond distances lie withi...
متن کاملcatena-Poly[[(5-bromopyridine-3-carboxylato)dimetyltin(IV)]-μ-5-bromopyridine-3-carboxylato]
The title compound, [Sn(CH(3))(2)(C(6)H(3)BrNO(2))(2)], possesses an infinite chain structure owing to the presence of Sn-N bridges between adjacent mol-ecules. The SnO(4)NC(2) centre has a distorted penta-gonal-bipyramidal geometry with the C atoms in the axial positions.
متن کاملPoly[[aqua(μ2-oxalato)(μ2-2-oxidopyridinium-3-carboxylato)holmium(III)] monohydrate]
In the title complex, {[Ho(C(2)O(4))(C(6)H(4)NO(3))(H(2)O)]·(H(2)O)}(n), the Ho(III) ion is coordinated by three O atoms from two 2-oxidopyridinium-3-carboxylate ligands, four O atoms from two oxalate ligands and one water mol-ecule in a distorted bicapped trigonal-prismatic geometry. The 2-oxidopyridin-ium-3-carboxylate and oxalate ligands link the Ho(III) ions into a layer in (100). These lay...
متن کاملPoly[diaqua(μ2-3-carboxypyrazine-2-carboxylato)(μ2-pyrazine-2,3-dicarboxylic acid)potassium(I)]
The structural unit of the title compound, [K(C(6)H(3)N(2)O(4))(C(6)H(4)N(2)O(4))(H(2)O)(2)](n), consists of one potassium cation, one hydrogen pyrazine-2,3-dicarboxyl-ate anion, one pyrazine-2,3-dicarboxylic acid mol-ecule and two water mol-ecules; this is twice the asymmetric unit, since the potassium cation lies on an inversion centre. Each anion or acid mol-ecule is linked to two potassium ...
متن کاملPoly[diaquatris(μ6-4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazine-2-carboxylato)tripotassium]
The asymmetric unit of the title compound, [K3(C4H2N3O4)3(H2O)2] n , contains two potassium cations (one in general position, one located on a twofold rotation axis), one and a half oxonate anions (the other half generated by twofold symmetry) and one water mol-ecule. As a result of the twofold symmetry, one H atom of the symmetric anion is statistically occupied. Both potassium cations are sur...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808033783